A route to explain water anomalies from results on an aqueous solution of salt

In this paper we investigate the possibility to detect the hypothesized liquid-liquid critical point of water in supercooled aqueous solutions of salts. Molecular dynamics computer simulations are conducted on bulk TIP4P water and on an aqueous solution of sodium chloride in TIP4P water, with concentration c = 0.67 mol/kg. The liquid-liquid critical point is found both in the bulk and in the solution. Its position in the thermodynamic plane shifts to higher temperature and lower pressure for the solution. Comparison with available experimental data allowed us to produce the phase diagrams of both bulk water and the aqueous solution as measurable in experiments. Given the position of the liquid-liquid critical point in the solution as obtained from our simulations, the experimental determination of the hypothesized liquid-liquid critical point of water in aqueous solutions of salts appears possible.Comment: 5 pages, 6 figures. Accepted for publication on the Journal of Chemical Physics (2010)

Structural Properties of High and Low Density Water in a Supercooled Aqueous Solution of Salt

We consider and compare the structural properties of bulk TIP4P water and of a sodium chloride aqueous solution in TIP4P water with concentration c = 0.67 mol/kg, in the metastable supercooled region. In a previous paper [D. Corradini, M. Rovere and P. Gallo, J. Chem. Phys. 132, 134508 (2010)] we found in both systems the presence of a liquid-liquid critical point (LLCP). The LLCP is believed to be the end point of the coexistence line between a high density liquid (HDL) and a low density liquid (LDL) phase of water. In the present paper we study the different features of water-water structure in HDL and LDL both in bulk water and in the solution. We find that the ions are able to modify the bulk LDL structure, rendering water-water structure more similar to the bulk HDL case. By the study of the hydration structure in HDL and LDL, a possible mechanism for the modification of the bulk LDL structure in the solution is identified in the substitution of the oxygen by the chloride ion in oxygen coordination shells.Comment: 10 pages, 10 figures, 2 tables. Accepted for publication on J. Phys. Chem

Driving extreme variability: The evolving corona and evidence for jet launching in Markarian 335

Variations in the X-ray emission from the narrow line Seyfert 1 galaxy, Markarian 335 (Mrk 335), are studied on both long and short timescales through observations made between 2006 and 2013 with XMM-Newton, Suzaku and NuSTAR. Changes in the geometry and energetics of the corona that give rise to this variability are inferred through measurements of the relativistically blurred reflection seen from the accretion disc. On long timescales, we find that during the high flux epochs the corona has expanded, covering the inner regions of the accretion disc out to a radius of 26(-7,+10)rg. The corona contracts to within 12rg and 5rg in the intermediate and low flux epochs, respectively. While the earlier high flux observation made in 2006 is consistent with a corona extending over the inner part of the accretion disc, a later high flux observation that year revealed that the X-ray source had become collimated into a vertically-extended jet-like corona and suggested relativistic motion of material upward. On short timescales, we find that an X-ray flare during a low flux epoch in 2013 corresponded to a reconfiguration from a slightly extended corona to one much more compact, within just 2~3rg of the black hole. There is evidence that during the flare itself, the spectrum softened and the corona became collimated and slightly extended vertically as if a jet-launching event was aborted. Understanding the evolution of the X-ray emitting corona may reveal the underlying mechanism by which the luminous X-ray sources in AGN are powered.Comment: 21 pages, 9 figures. Accepted for publication in MNRA

Seyfert galaxies with Swift: giant flares, rapid drops, and other surprises

Swift has initiated a new era of understanding the extremes of active galactic nuclei (AGN) variability, their drivers and underlying physics. This is based on its rapid response, high sensitivity, good spatial resolution, and its ability to collect simultaneously X--ray-to-optical SEDs. Here, we present results from our recent monitoring campaigns with Swift of highly variable AGN, including outbursts, deep low states, and unusual long-term trends in several Seyfert galaxies including Mrk 335, WPVS007, and RXJ2314.9+2243. We also report detection of a new X-ray and optical outburst of IC 3599 and our Swift follow-ups. IC 3599 was previously known as one of the AGN with the highest-amplitude outbursts. We briefly discuss implications of this second outburst of IC 3599 for emission scenarios including accretion-disk variability, repeat tidal disruption events, and the presence of a binary supermassive black hole.Comment: to appear in "Swift: 10 years of discovery", Proceedings of Scienc

Hodge polynomials of the moduli spaces of pairs

Let $X$ be a smooth projective curve of genus $g\geq 2$ over the complex numbers. A holomorphic pair on $X$ is a couple $(E,\phi)$, where $E$ is a holomorphic bundle over $X$ of rank $n$ and degree $d$, and $\phi\in H^0(E)$ is a holomorphic section. In this paper, we determine the Hodge polynomials of the moduli spaces of rank 2 pairs, using the theory of mixed Hodge structures. We also deal with the case in which $E$ has fixed determinant.Comment: 23 pages, typos added, minor change

Probing the geometry and motion of AGN coronae through accretion disc emissivity profiles

To gain a better understanding of the inner disc region that comprises active galactic nuclei it is necessary to understand the pattern in which the disc is illuminated (the emissivity profile) by X-rays emitted from the continuum source above the black hole (corona). The differences in the emissivity profiles produced by various corona geometries are explored via general relativistic ray tracing simulations. Through the analysis of various parameters of the geometries simulated it is found that emissivity profiles produced by point source and extended geometries such as cylindrical slabs and spheroidal coronae placed on the accretion disc are distinguishable. Profiles produced by point source and conical geometries are not significantly different, requiring an analysis of reflection fraction to differentiate the two geometries. Beamed point and beamed conical sources are also simulated in an effort to model jet-like coronae, though the differences here are most evident in the reflection fraction. For a point source we determine an approximation for the measured reflection fraction with the source height and velocity. Simulating spectra from the emissivity profiles produced by the various geometries produce distinguishable differences. Overall spectral differences between the geometries do not exceed 15 per cent in the most extreme cases. It is found that emissivity profiles can be useful in distinguishing point source and extended geometries given high quality spectral data of extreme, bright sources over long exposure times. In combination with reflection fraction, timing, and spectral analysis we may use emissivity profiles to discern the geometry of the X-ray source.Comment: 15 pages, 12 figures. Accepted for publication in MNRA

Mrk 1014: An AGN Dominated ULIRG at X-rays

In this paper we report on an XMM-Newton observation of the ultraluminous infrared QSO Mrk 1014. The X-ray observation reveals a power-law dominated (photon index of about 2.2) spectrum with a slight excess in the soft energy range. AGN and starburst emission models fit the soft excess emission equally well, however, the most plausible explanation is an AGN component as the starburst model parameter, temperature and luminosity, appear physically unrealistic. The mean luminosity of Mrk 1014 is about 2 times 10^44 erg s^-1. We have also observed excess emission at energies greater than 5 keV. This feature could be attributed to a broadened and redshifted iron complex, but deeper observations are required to constrain its origin. The light curve shows small scale variability over the 11 ks observation. There is no evidence of intrinsic absorption in Mrk 1014. The X-ray observations support the notion of an AGN dominated central engine. We establish the need for a longer observation to constrain more precisely the nature of the X-ray components.Comment: 5 pages incl. 3 figures, MNRAS in pres

Anomalous relaxation kinetics and charge density wave correlations in underdoped BaPb1-xBixO3

Superconductivity often emerges in proximity of other symmetry-breaking ground states, such as antiferromagnetism or charge-density-wave (CDW) order. However, the subtle inter-relation of these phases remains poorly understood, and in some cases even the existence of short-range correlations for superconducting compositions is uncertain. In such circumstances, ultrafast experiments can provide new insights, by tracking the relaxation kinetics following excitation at frequencies related to the broken symmetry state. Here, we investigate the transient terahertz conductivity of BaPb1-xBixO3 - a material for which superconductivity is adjacent to a competing CDW phase - after optical excitation tuned to the CDW absorption band. In insulating BaBiO3 we observed an increase in conductivity and a subsequent relaxation, which are consistent with quasiparticles injection across a rigid semiconducting gap. In the doped compound BaPb0.72Bi0.28O3 (superconducting below Tc=7K), a similar response was also found immediately above Tc. This observation evidences the presence of a robust gap up to T=40 K, which is presumably associated with short-range CDW correlations. A qualitatively different behaviour was observed in the same material fo T>40 K. Here, the photo-conductivity was dominated by an enhancement in carrier mobility at constant density, suggestive of melting of the CDW correlations rather than excitation across an optical gap. The relaxation displayed a temperature dependent, Arrhenius-like kinetics, suggestive of the crossing of a free-energy barrier between two phases. These results support the existence of short-range CDW correlations above Tc in underdoped BaPb1-xBixO3, and provide new information on the dynamical interplay between superconductivity and charge order.Comment: 19 pages, 4 figure